Kimia Koordinasi: d3 Microstate dan Term Symbol


Tabel d3 Microstate


-1 1/2
-1/2
+1/2
+11/2
+5
-
2+ 2- 1-
2+  2- 1+
-
+4
-
2+ 2- 0-
2+ 2- 0+
-

2- 1- 1+
2+ 1+ 1-

+3
2- 1- 0-
2+ 1- 0-
2+ 1- 0+
2+ 1+ 0+

2- 1+ 0-
- 1+ 0+


2- 1- 0+
2+ 2- -1+


2- 2+ -1-
2+ 1+ 0-

+2
2- 1- -1-
2+ 1- -1-
2+ 2- -2+
2+ 1+ -1+

2- 1- -1+
2- 1+ -1+


2- 1+ -1-
2+ 1- -1+


2+ 2- -2-
2+ 1+ -1-


1+ 1- 0-
2+ 0- 0+


2- 0+ 0-
1-1+ 0+

+1
2- 1- -2-
2- 1- -2+
2- 1+ -2+
2+ 1+ -2+
2- 0- -1-
2- 1+ -2+
2+ 1- -2+
2+ 0+ -1+

2- 0- -1+
2+ 0- -1+


2- 0+ -1-
1+1- -1+


2+ 1- -2-
2-0+ -1+


2+ 0- -1-
2+ 1+ -2-


1+ 1- -1-
2+ 0+ -1-


1-0+ 0-
1+0+0-

0
2- 0- -2-
2+ 0- -2-
2+ 0+ -2-
2+ 0+ -2+
1- 0- -1-
2- 0+ -2-
2+ 0- -2+
1+ 0- -1+

1+ 1- -2-
2- 0+ -2+


2- 0- -2+
1+1- -2+


2- -1+ -1-
2+ -1+ -1-


1+ 0- -1-
1+ 0+ -1-


1-0+ -1-
1+ 0- -1+


1-0- -1-
1-0+ -1+

-1
1- 0- -2-
0+ 0- -1-
0+ 0- -1+
1+ 0+-2+
2--1--2-
2- -1- -2+
2- -1+ -2+
2+-1+-2+

2+ -1- -2-
2+ -1+ -2-


1- 0- -2+
2+ -1- -2+


1- -1+ -1-
1+ 0+ -2-


2- -1+ -2-
1- 0+ -2+


1- 0+ -2-
1+ 0- -2+


1+ 0- -2-
1+ -1+ -1-

-2
1- -1- -2-
1+ -1- -2-
1+ -1+ -2-
1+-1+-2+

1- -1- -2+
1+ -1- -2+


1- -1+ -2-
1- -1+ -2+


2- -2+ -2-
2+ -2+ -2-


0- -1+ -1-
0+ -1+ -1-


0+ 0- -2-
0+ 0- -2+

-3
0- -1- -2-
0+ -1- -2-
0+ -1+ -2-
0+-1+-2+

0- -1- -2+
0- -1+ -2+


0- -1+ -2-
0+ -1- -2+


1- -2+ -2-
1+ -2+ -2-

-4
-
0- -2+ -2-
0+ -2+ -2-
-

-1+ -1- -2-
-1+ -1- -2+

-5
-
-1- -2+ -2-
-1+ -2+ -2-
-

Term Symbol untuk Konfigurasi d3
ML/MS
-1 1/2
-1/2
+1/2
+11/2
+5

x
x

+4

x x
x x

+3
x
x x x x
x x x x
x
+2
x
x x x x x x
x x x x x x
x
+1
x x
x x x x x x x x
x x x x x x x x
x x
0
x x
x x x x x x x x
x x x x x x x x
x x
-1
x x
x x x x x x x x
x x x x x x x x
x x
-2
x
x x x x x x
x x x x x x
x
-3
x
x x x x
x x x x
x
-4

x x
x x

-5

x
x


Term Symbol :
4F, 4P, 2H, 2G, 2F, 2D, 2D, 2P
Ground State : 4F
Karena 4F memiliki nilai multiplisitas terbesar. Selain itu jika dibandingkan dengan nilai multiplisitas tertinggi lainnya (4P), 4F memiliki nilai L yang lebih besar.
Ground state diperoleh pada nilai multiplisitas dan nilai L yang terbesar. Sehingga Ground State pada konfigurasi d3 adalah 4F

1 komentar:

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